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Stereochemistry of electrophilic attack at 34e(−) dimetallic complexes: the case of diiron dithiolato carbonyls + MeS(+)
Experimental and computational experiments show that the electrophile MeS(+) attacks a single Fe center in Fe(2)(propanedithiolate)(CO)(4)(PMe(3))(2) followed by isomerization of this terminal thiolato complex to the corresponding μ-SMe derivative.
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| 主要な著者: | , , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2011
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3465568/ https://ncbi.nlm.nih.gov/pubmed/21776614 |
| タグ: |
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