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Desymmetrized Diiron Azadithiolato Carbonyls: A Step Toward Modeling the Iron-Only Hydrogenases
Condensation of Fe(2)(SH)(2)(CO)(6), acetaldehyde, and (NH(4))(2)CO(3) affords the methyl-substituted azadithiolate Fe(2)[(SCHMe)(2)NH](CO)(6) (1). The complex exists mainly (~95%) as the meso diastereomer, but the d,l diastereoisomers could be detected. DFT calculations predict that the meso isomer...
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| 主要な著者: | , , , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2008
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2427274/ https://ncbi.nlm.nih.gov/pubmed/18552987 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om7009599 |
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