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Diiron Azamonothiolates via Scission of Dithiadiazacyclooctanes by Iron Carbonyls
The reaction of Fe(3)(CO)(12) with the dithiadiazacyclooctanes [SCH(2)N(R)CH(2)](2) affords Fe(2)[SCH(2)N(Me)CH(2)](CO)(6) (R = Me, Bn). The methyl derivative 1(Me) was characterized crystallographically (Fe-Fe = 2.5702(5) Å). Its low symmetry is verified by variable temperature (13)C NMR spectrosco...
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| Publicado no: | Eur J Inorg Chem |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4493438/ https://ncbi.nlm.nih.gov/pubmed/26167130 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201402413 |
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