Diiron Azamonothiolates via Scission of Dithiadiazacyclooctanes by Iron Carbonyls

The reaction of Fe(3)(CO)(12) with the dithiadiazacyclooctanes [SCH(2)N(R)CH(2)](2) affords Fe(2)[SCH(2)N(Me)CH(2)](CO)(6) (R = Me, Bn). The methyl derivative 1(Me) was characterized crystallographically (Fe-Fe = 2.5702(5) Å). Its low symmetry is verified by variable temperature (13)C NMR spectrosco...

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Publicat a:Eur J Inorg Chem
Autors principals: Lin, Tai, Ulloa, Olbelina A., Rauchfuss, Thomas B., Gray, Danielle L.
Format: Artigo
Idioma:Inglês
Publicat: 2014
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Article
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4493438/
https://ncbi.nlm.nih.gov/pubmed/26167130
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201402413
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