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Studies on the Condensation Pathway to and Properties of Diiron Azadithiolate Carbonyls
Reaction of Fe(2)(SH)(2)(CO)(6) and HCHO, which gives Fe(2)[(SCH(2))(2)NH](CO)(6) in the presence of NH(3), affords the possible intermediate Fe(2)(SCH(2)OH)(2)(CO)(6), which has been characterized crystallographically as its axial–equatorial isomer. Fe(2)(SCH(2)OH)(2)(CO)(6) was shown to react with...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2007
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2441914/ https://ncbi.nlm.nih.gov/pubmed/18592045 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om0611150 |
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