One-electron oxidation of an oxoiron(IV) complex to form an [O═Fe(V)═NR](+) center

Oxoiron(V) species are postulated to be involved in the mechanisms of the arene cis-dihydroxylating Rieske dioxygenases and of bioinspired nonheme iron catalysts for alkane hydroxylation, olefin cis-dihydroxylation, and water oxidation. In an effort to obtain a synthetic oxoiron(V) complex, we repor...

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Main Authors: Van Heuvelen, Katherine M., Fiedler, Adam T., Shan, Xiaopeng, De Hont, Raymond F., Meier, Katlyn K., Bominaar, Emile L., Münck, Eckard, Que, Lawrence
Format: Artigo
Sprog:Inglês
Udgivet: National Academy of Sciences 2012
Fag:
Physical Sciences
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3409744/
https://ncbi.nlm.nih.gov/pubmed/22786933
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1206457109
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