An Ultra-Stable Oxoiron(IV) Complex and Its Blue Conjugate Base

Treatment of [Fe(II)(L)](OTf)(2) (4), (where L = 1,4,8-Me(3)cyclam-11-CH(2)C(O)NMe(2)) with iodosylbenzene yielded the corresponding S = 1 oxoiron(IV) complex [Fe(IV)(O(L)](OTf)(2) (5) in nearly quantitative yield. The remarkably high stability of 5 (t(1/2) ≈ 5 days at 25 °C) facilitated its charact...

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Main Authors: England, Jason, Bigelow, Jennifer O., Van Heuvelen, Katherine M., Farquhar, Erik R., Martinho, Marléne, Meier, Katlyn K., Frisch, Jonathan R., Münck, Eckard, Que, Lawrence
Formato: Artigo
Idioma:Inglês
Publicado: 2013
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3956701/
https://ncbi.nlm.nih.gov/pubmed/24660055
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C3SC52755G
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