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An Ultra-Stable Oxoiron(IV) Complex and Its Blue Conjugate Base
Treatment of [Fe(II)(L)](OTf)(2) (4), (where L = 1,4,8-Me(3)cyclam-11-CH(2)C(O)NMe(2)) with iodosylbenzene yielded the corresponding S = 1 oxoiron(IV) complex [Fe(IV)(O(L)](OTf)(2) (5) in nearly quantitative yield. The remarkably high stability of 5 (t(1/2) ≈ 5 days at 25 °C) facilitated its charact...
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| Main Authors: | , , , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3956701/ https://ncbi.nlm.nih.gov/pubmed/24660055 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C3SC52755G |
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