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One-electron oxidation of an oxoiron(IV) complex to form an [O═Fe(V)═NR](+) center
Oxoiron(V) species are postulated to be involved in the mechanisms of the arene cis-dihydroxylating Rieske dioxygenases and of bioinspired nonheme iron catalysts for alkane hydroxylation, olefin cis-dihydroxylation, and water oxidation. In an effort to obtain a synthetic oxoiron(V) complex, we repor...
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| Autori principali: | , , , , , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
National Academy of Sciences
2012
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3409744/ https://ncbi.nlm.nih.gov/pubmed/22786933 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1206457109 |
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