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A Formal Synthesis of (−)-Englerin A by RRCM and Transannular Etherification
[Image: see text] A bicyclization approach to englerin A has culminated in a formal asymmetric total synthesis. Key transformations in the 10-step sequence are a regiospecific epoxide opening and a relay ene-yne-ene metathesis that converts linear substrates specifically to Δ(4,6)-guaiadiene-9,10 di...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3390928/ https://ncbi.nlm.nih.gov/pubmed/22564056 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol3007524 |
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