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Concise Formal Synthesis of the Pseudopterosins via Anionic Oxy-Cope/Transannular Michael Addition Cascade
An anionic oxy-Cope/transannular Michael addition cascade converts a spirocyclic architecture—readily available by Diels–Alder cycloaddition—into the hydrophenalene carbon skeleton of the pseudopterosin aglycones. Oxidation of the resulting cyclohexenone ring to the catechol that is characteristic o...
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| Publicado no: | Org Lett |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7278522/ https://ncbi.nlm.nih.gov/pubmed/32077289 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c00486 |
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