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Concise Formal Synthesis of the Pseudopterosins via Anionic Oxy-Cope/Transannular Michael Addition Cascade

An anionic oxy-Cope/transannular Michael addition cascade converts a spirocyclic architecture—readily available by Diels–Alder cycloaddition—into the hydrophenalene carbon skeleton of the pseudopterosin aglycones. Oxidation of the resulting cyclohexenone ring to the catechol that is characteristic o...

詳細記述

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書誌詳細
出版年:Org Lett
主要な著者: Ramella, Vincenzo, Roosen, Philipp C., Vanderwal, Christopher D.
フォーマット: Artigo
言語:Inglês
出版事項: 2020
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC7278522/
https://ncbi.nlm.nih.gov/pubmed/32077289
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c00486
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