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Enantioselective Formal Synthesis of (−)-Englerin A via a Rh-catalyzed [4+3] Cycloaddition Reaction
[Image: see text] An enantioselective formal synthesis of (−)-englerin A (1) is reported. Key to the strategy is a Rh-catalyzed [4+3] cycloaddition reaction between furan 10 and diazoester 11 that, following an intramolecular aldol condensation, produces the tri-cyclic scaffold of englerin. This str...
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| Huvudupphovsmän: | , , |
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| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2010
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2927118/ https://ncbi.nlm.nih.gov/pubmed/20669919 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol1015652 |
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