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Importance of a 4-Alkyl Substituent for Activity in the Englerin Series

[Image: see text] The ring closing metathesis/transannular etherification approach to the englerin nucleus was adapted to provide two key intermediates for analogue synthesis: the 4-desmethyl Δ(5,6) tricycle and the 4-oxo Δ(5,6) tricycle. The former was elaborated to 4-desmethyl englerin A and the l...

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Publicat a:ACS Med Chem Lett
Autors principals: Elliott, Daniel C., Beutler, John A., Parker, Kathlyn A.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2017
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5512125/
https://ncbi.nlm.nih.gov/pubmed/28740610
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsmedchemlett.7b00161
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