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Oxy-Intermediates of Homoprotocatechuate 2,3-Dioxygenase: Facile Electron Transfer Between Substrates
Substrates homoprotocatechuate (HPCA) and O(2) bind to the Fe(II) of Homoprotocatechuate 2,3-dioxygenase (FeHPCD) in adjacent coordination sites. Transfer of an electron(s) from HPCA to O(2) via the iron is proposed to activate the substrates for reaction with each other to initiate aromatic ring cl...
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| Главные авторы: | , , , , , , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2011
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3222778/ https://ncbi.nlm.nih.gov/pubmed/22011290 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi201436n |
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