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Oxidation of Peptides by Methyl(trifluoromethyl)dioxirane: the Protecting Group Matters
Representative Boc protected and acetyl protected peptide methyl esters bearing alkyl side chains undergo effective oxidation using methyl(trifluoromethyl)dioxirane (1b) under mild conditions. We observe a protecting group dependency in the chemoselectivity displayed by the dioxirane 1b. N-hydroxyla...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3220948/ https://ncbi.nlm.nih.gov/pubmed/17221970 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo061910n |
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