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Protecting group free radical C–H trifluoromethylation of peptides
Two radical-based approaches have been developed to effect the trifluoromethylation of aryl C–H bonds in native peptides either using stoichiometric oxidant or visible light photoredox catalysis. The reported methods are able to derivatize tyrosine and tryptophan sidechains under biocompatible condi...
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| Publicado en: | Chem Sci |
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| Main Authors: | , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
Royal Society of Chemistry
2018
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5941281/ https://ncbi.nlm.nih.gov/pubmed/29780547 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc00368h |
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