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Concerning Selectivity in the Oxidation of Peptides by Dioxiranes. Further Insight into the Effect of Carbamate Protecting Groups
Using methyl(trifluoromethyl)dioxirane (TFDO), the oxidation of some tripeptide esters protected at the N-terminus with carbamate or amide groups could be achieved efficiently under mild conditions with no loss of configuration at the chiral centers. Expanding on preliminary investigations, it is fo...
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| Autores principales: | , , , , , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2010
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2922685/ https://ncbi.nlm.nih.gov/pubmed/20560586 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo100855h |
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