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Selective Synthesis of Hydroxy Analogues of Valinomycin using Dioxiranes
[Image: see text] A synthesis of representative monohydroxy derivatives of valinomycin (VLM) was achieved under mild conditions by direct hydroxylation at the side-chains of the macrocyclic substrate using dioxiranes. Results demonstrate that the powerful methyl(trifluoromethyl)dioxirane 1b should b...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3205966/ https://ncbi.nlm.nih.gov/pubmed/21905749 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol201971v |
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