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Highly Enantioselective CH Oxidation of vic-Diols with Shi’s Oxazolidinone Dioxiranes
Through an analogical study of the transition states of CH oxidation and asymmetric epoxidation of terminal alkenes, the first dioxirane-mediated catalytic highly enantioselective CH oxidation method was realized with the Shi’s oxazolidinone ketone derivatives. Very good enantioselectivity (up to 92...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2593872/ https://ncbi.nlm.nih.gov/pubmed/16805540 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol060904a |
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