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Organocatalytic High Enantioselective Synthesis of β-Formyl-α-hydroxyphosphonates
[Image: see text] The cross aldol reaction between enolizable aldehydes and α-ketophosphonates was achieved for the first time by using 9-amino-9-deoxy-epi-quinine as the catalyst. β-Formyl-α-hydroxyphosphonates were obtained in high to excellent enantioselectivities. The reaction works especially w...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3170695/ https://ncbi.nlm.nih.gov/pubmed/21918646 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201000835 |
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