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Organocatalytic High Enantioselective Synthesis of β-Formyl-α-hydroxyphosphonates

[Image: see text] The cross aldol reaction between enolizable aldehydes and α-ketophosphonates was achieved for the first time by using 9-amino-9-deoxy-epi-quinine as the catalyst. β-Formyl-α-hydroxyphosphonates were obtained in high to excellent enantioselectivities. The reaction works especially w...

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Hlavní autoři: Perera, Sandun, Naganaboina, Vijaya Kumar, Wang, Long, Zhang, Bin, Guo, Qunsheng, Rout, Laxmidhar, Zhao, Cong-Gui
Médium: Artigo
Jazyk:Inglês
Vydáno: 2011
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3170695/
https://ncbi.nlm.nih.gov/pubmed/21918646
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201000835
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