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Organocatalytic Enantioselective Synthesis of Both Diastereomers of α-Hydroxyphosphinates
Racemic α-acylphosphinates and formylphosphinate hydrate were used directly as the substrates in a proline derivative-catalyzed cross aldol reaction with ketones. Because of the preexisting the phosphorus stereogenic center, a mixture of two diastereomers of the corresponding α-hydroxyphosphinates w...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2821456/ https://ncbi.nlm.nih.gov/pubmed/20085234 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo9022099 |
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