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Organocatalytic Highly Enantioselective Tandem Michael-Knoevenagel Reaction for the Synthesis of Substituted Thiochromanes

Enantioenriched tetrasubstituted thiochromanes have been synthesized using a tandem Michael addition-Knoevenagel reaction between 2-mercaptobenzaldehydes and benzylidenemalonates with a 9-epi-aminoquinine thiourea derivative as the catalyst. Steric and electron effects were found to affect profoundl...

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Bibliografiske detaljer
Main Authors: Dodda, Rajasekhar, Mandal, Tanmay, Zhao, Cong-Gui
Format: Artigo
Sprog:Inglês
Udgivet: 2008
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2350192/
https://ncbi.nlm.nih.gov/pubmed/19295905
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2008.01.113
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