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Active intermediates in heme mono reactions as revealed by cryoreduction/annealing, EPR/ENDOR studies

This review describes the use of cryoreduction/annealing EPR/ENDOR techniques for determining the active oxidizing species in reactions catalyzed by heme monooxygenases. The three candidate heme states are: ferric peroxo, ferric hydroperoxo, and Compound I intermediates. The enzymes discussed includ...

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Detalhes bibliográficos
Main Authors: Davydov, Roman, Hoffman, Brian M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3021649/
https://ncbi.nlm.nih.gov/pubmed/20854788
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.abb.2010.09.013
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