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Active intermediates in heme mono reactions as revealed by cryoreduction/annealing, EPR/ENDOR studies
This review describes the use of cryoreduction/annealing EPR/ENDOR techniques for determining the active oxidizing species in reactions catalyzed by heme monooxygenases. The three candidate heme states are: ferric peroxo, ferric hydroperoxo, and Compound I intermediates. The enzymes discussed includ...
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Main Authors: | , |
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Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
2010
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3021649/ https://ncbi.nlm.nih.gov/pubmed/20854788 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.abb.2010.09.013 |
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