Fe(I)-mediated reductive cleavage and coupling of CO(2): An Fe(II)(μ-O,μ -CO)Fe(II) core

THF solutions of a new iron(I) source, “[PhBP(CH2Cy)(3)]Fe” ([PhBP(CH2Cy)(3)] = [PhBP(CH(2)P(CH(2)Cy)(2))(3)](−)), effect the reductive cleavage of CO(2) via O-atom transfer at ambient temperature. The dominant reaction pathway is bimetallic and leads to the formation of a structurally unprecedented...

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Bibliografiska uppgifter
Huvudupphovsmän: Lu, Connie C., Saouma, Caroline T., Day, Michael W., Peters, Jonas C.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2007
Ämnen:
Article
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC2888261/
https://ncbi.nlm.nih.gov/pubmed/17199260
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja065524z
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