Product Deuterium Isotope Effects for Orotidine 5'-Monophosphate Decarboxylase: Effect of Changing Substrate and Enzyme Structure on the Partitioning of the Vinyl Carbanion Reaction Intermediate

A product deuterium isotope effect (PIE) of 1.0 was determined as the ratio of the yields of [6-(1)H]-uridine 5'-monophosphate (50%) and [6-(2)H]-uridine 5'-monophosphate (50%) from the decarboxylation of orotidine 5'-monophosphate (OMP) in 50/50 (v/v) HOH/DOD catalyzed by orotidine 5...

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Detalhes bibliográficos
Main Authors: Toth, Krisztina, Amyes, Tina L., Wood, Bryant M., Chan, Kui, Gerlt, John A., Richard, John P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2876347/
https://ncbi.nlm.nih.gov/pubmed/20441167
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja102408k
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