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Measurement of the Intramolecular Isotope Effect on Aliphatic Hydroxylation by Chromobacterium violaceum Phenylalanine Hydroxylase

[Image: see text] The non-heme iron enzyme phenylalanine hydroxylase from Chromobacterium violaceum has previously been shown to catalyze the hydroxylation of benzylic and aliphatic carbons in addition to the normal aromatic hydroxylation reaction. The intrinsic isotope effect for hydroxylation of 3...

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Detalhes bibliográficos
Main Authors: Panay, Aram J., Fitzpatrick, Paul F.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2858384/
https://ncbi.nlm.nih.gov/pubmed/20355730
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja101563t
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