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A Conserved Lysine in β-Lactam Synthetase Assists Ring Cyclization: Implications for Clavam and Carbapenem Biosynthesis
β-Lactam synthetase (β-LS) is the paradigm of a growing class of enzymes that form the critical β-lactam ring in the clavam and carbapenem antibiotics. β-LS catalyzes a two stage reaction in which N(2)-(2-carboxyethyl)-l-arginine is first adenylated, and then undergoes intramolecular ring closure. I...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2833277/ https://ncbi.nlm.nih.gov/pubmed/19882698 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cbic.200900389 |
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