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Direct, Catalytic Hydroaminoalkylation of Unactivated Olefins with N-Alkyl Arylamines
[Image: see text] A tantalum-catalyzed addition of N-alkylarylamine α-C–H bonds across olefins is reported. These reactions occur with mono- and 2,2-disubstituted olefins to form the branched insertion products in high yield and regioselectivity. The reactions encompass additions of the α-C–H bonds...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2590937/ https://ncbi.nlm.nih.gov/pubmed/17474747 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0718366 |
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