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Direct and Stereospecific Synthesis of N–H and N–Alkyl Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acids()
Herein we report a Rh(II)-catalyzed direct and stereospecific N–H- and N–alkyl aziridination of olefins that uses hydroxylamine-O-sulfonic acids as inexpensive, readily available and nitro group-free aminating reagents. Unactivated olefins, featuring a wide range of functional groups, are converted...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5727000/ https://ncbi.nlm.nih.gov/pubmed/28614619 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201705530 |
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