Llwytho...
Iridium-Catalyzed, Hydrosilyl-Directed Borylation of Unactivated Alkyl C−H Bonds
We report the iridium-catalyzed borylation of primary and secondary alkyl C−H bonds directed by a Si−H group to form alkylboronate esters site selectively. The reactions occur with high selectivity at primary C−H bonds γ to the hydrosilyl group to form primary alkyl bisboronate esters. In the absenc...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | J Am Chem Soc |
|---|---|
| Prif Awduron: | , , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
2016
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4809204/ https://ncbi.nlm.nih.gov/pubmed/26745739 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b12153 |
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