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Iridium-Catalyzed, Hydrosilyl-Directed Borylation of Unactivated Alkyl C−H Bonds
We report the iridium-catalyzed borylation of primary and secondary alkyl C−H bonds directed by a Si−H group to form alkylboronate esters site selectively. The reactions occur with high selectivity at primary C−H bonds γ to the hydrosilyl group to form primary alkyl bisboronate esters. In the absenc...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4809204/ https://ncbi.nlm.nih.gov/pubmed/26745739 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b12153 |
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