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Mechanism of the Iridium-Catalyzed Silylation of Aromatic C–H Bonds

Phenanthroline ligands and [Ir(cod)(OMe)](2) form complexes that catalyze the silylation of aromatic and aliphatic C–H bonds. However, no experimental data on the identity of complexes related to the mechanism of this process or the mechanisms by which they react to functionalize C–H bonds have been...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Karmel, Caleb, Hartwig, John F.
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7660231/
https://ncbi.nlm.nih.gov/pubmed/32375477
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c03301
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