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Rhodium-Catalyzed Regioselective Silylation of Alkyl C–H Bonds for the Synthesis of 1,4-Diols
A rhodium-catalyzed intramolecular silylation of alkyl C–H bonds has been developed that occurs with unusual selectivity for the C–H bonds located δ to the oxygen atom of an alcohol-derived silyl ether over typically more reactive C–H bonds more proximal to the same oxygen atom. (Hydrido)silyl ether...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5810544/ https://ncbi.nlm.nih.gov/pubmed/29293327 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b11964 |
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