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Rhodium-Catalyzed Regioselective Silylation of Alkyl C–H Bonds for the Synthesis of 1,4-Diols

A rhodium-catalyzed intramolecular silylation of alkyl C–H bonds has been developed that occurs with unusual selectivity for the C–H bonds located δ to the oxygen atom of an alcohol-derived silyl ether over typically more reactive C–H bonds more proximal to the same oxygen atom. (Hydrido)silyl ether...

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書目詳細資料
發表在:J Am Chem Soc
Main Authors: Karmel, Caleb, Li, Bijie, Hartwig, John F.
格式: Artigo
語言:Inglês
出版: 2018
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC5810544/
https://ncbi.nlm.nih.gov/pubmed/29293327
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b11964
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