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Iridium-Catalyzed Silylation of C–H Bonds in Unactivated Arenes: A Sterically Encumbered Phenanthroline Ligand Accelerates Catalysis
We report a new system for the silylation of aryl C–H bonds. The combination of [Ir(cod)(OMe)](2) and 2,9-Me(2)-phenanthroline (2,9-Me(2)-phen) catalyzes the silylation of arenes at lower temperatures and with faster rates than those reported previously, when the hydrogen byproduct is removed, and w...
Enregistré dans:
| Publié dans: | J Am Chem Soc |
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| Auteurs principaux: | , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2019
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6839914/ https://ncbi.nlm.nih.gov/pubmed/30971087 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b01972 |
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