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Iridium-Catalyzed Silylation of Five-Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl-Imidazoline Ligand
The steric effects of substituents on five-membered rings are less pronounced than those on six-membered rings because of the difference in bond angles. Thus, the regioselectivities of reactions that occur with selectivities dictated by steric effects, such as the borylation of C-H bonds, have been...
Tallennettuna:
| Julkaisussa: | Angew Chem Weinheim Bergstr Ger |
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| Päätekijät: | , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2020
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7566956/ https://ncbi.nlm.nih.gov/pubmed/33071367 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ange.201916015 |
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