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Iridium-Catalyzed Silylation of Unactivated C-H Bonds

The functionalization of primary C-H bonds has been a longstanding challenge in catalysis. Our group has developed a series of silylations of primary C-H bonds that occur with site selectivity and diastereoselectivity resulting from an approach to run the reactions as intramolecular processes. These...

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Vydáno v:Tetrahedron
Hlavní autoři: Hartwig, John F., Romero, Erik A.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2019
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6853617/
https://ncbi.nlm.nih.gov/pubmed/31723309
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2019.05.055
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