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Hydroaminoalkylation of Unactivated Olefins with Dialkylamines
The intermolecular addition of the α-C–H bonds of unactivated dialkylamines to olefins in the presence of the chloro amido complex [TaCl(3)(NEt(2))(2)](2) (2) is described. This process forms the branched insertion products in high yields (up to 96%) and selectivities, and represents a rare example...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4852863/ https://ncbi.nlm.nih.gov/pubmed/18937477 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja806367e |
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