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Mechanistic Insight into N=N Cleavage by a Low-Coordinate Iron(II) Hydride Complex
The reaction pathways of high-spin iron hydride complexes are relevant to the mechanism of N(2) reduction by nitrogenase, which has been postulated to involve paramagnetic iron-hydride species. However, almost all known iron hydrides are low-spin, diamagnetic Fe(II) compounds. We have demonstrated t...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2548314/ https://ncbi.nlm.nih.gov/pubmed/17564444 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja069199r |
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