Loading...

Diazoalkanes in Low-Coordinate Iron Chemistry: Bimetallic Diazoalkyl and Alkylidene Complexes of Iron(II)

Addition of trimethylsilyldiazomethane and its conjugate base to β-diketiminate-iron precursors gives novel dinuclear complexes in which the bridges are either diazomethane derivatives or an alkylidene. One product is an unusual bridging alkylidene complex containing two three-coordinate iron(II) ce...

Full description

Saved in:
Bibliographic Details
Published in:Inorg Chem
Main Authors: Reesbeck, Megan E., Grubel, Katarzyna, Kim, Daniel, Brennessel, William W., Mercado, Brandon Q., Holland, Patrick L.
Format: Artigo
Language:Inglês
Published: 2017
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5499981/
https://ncbi.nlm.nih.gov/pubmed/28067506
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.6b01952
Tags: Add Tag
No Tags, Be the first to tag this record!