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Reduction of CO(2) to CO using Low-Coordinate Iron: Formation of a Four-Coordinate Iron Dicarbonyl Complex and a Bridging Carbonate Complex
A reduced diiron(I) complex reacts with CO(2) to give two iron-containing products. One product has a carbonate bridge, which isomerizes rapidly at −70 °C and may be derived from an oxodiiron intermediate. Formation of this product releases free CO, which leads to a four-coordinate iron dicarbonyl c...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2474856/ https://ncbi.nlm.nih.gov/pubmed/18171059 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic701914m |
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