Wird geladen...

Reduction of CO(2) to CO using Low-Coordinate Iron: Formation of a Four-Coordinate Iron Dicarbonyl Complex and a Bridging Carbonate Complex

A reduced diiron(I) complex reacts with CO(2) to give two iron-containing products. One product has a carbonate bridge, which isomerizes rapidly at −70 °C and may be derived from an oxodiiron intermediate. Formation of this product releases free CO, which leads to a four-coordinate iron dicarbonyl c...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: Sadique, Azwana R., Brennessel, William W., Holland, Patrick L.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2008
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2474856/
https://ncbi.nlm.nih.gov/pubmed/18171059
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic701914m
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!