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A Formal [3,3]-Sigmatropic Rearrangement Route to Quaternary α-Vinyl Amino Acids: Use of Allylic N-PMP Trifluoroacetimidates
Pd(II)-mediated rearrangement of allylic N-PMP (p-methoxyphenyl) trifluoroacetimidates provides the first formal sigmatropic route to quaternary, α-vinylic amino acids, potential suicide substrates for PLP-enzymes. The amino acid side chains enter via transition metal-mediated C-C bond constructions...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2504469/ https://ncbi.nlm.nih.gov/pubmed/16494487 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol060019s |
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