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Lewis Acid Catalyzed [1,3]-Sigmatropic Rearrangement of Vinyl Aziridines
[Image: see text] This communication details the copper catalyzed ring expansion of vinyl aziridines to 3-pyrrolines. Broad substrate scope (24 examples) using tosyl and phthalimide protected vinyl aziridine substrates is observed. Cu(hfacac)(2) was determined to be superior to all other catalysts t...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2646081/ https://ncbi.nlm.nih.gov/pubmed/18841992 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol802123e |
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