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Lewis Acid Catalyzed [1,3]-Sigmatropic Rearrangement of Vinyl Aziridines

[Image: see text] This communication details the copper catalyzed ring expansion of vinyl aziridines to 3-pyrrolines. Broad substrate scope (24 examples) using tosyl and phthalimide protected vinyl aziridine substrates is observed. Cu(hfacac)(2) was determined to be superior to all other catalysts t...

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Détails bibliographiques
Auteurs principaux: Brichacek, Matthew, Lee, DongEun, Njardarson, Jon T.
Format: Artigo
Langue:Inglês
Publié: 2008
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC2646081/
https://ncbi.nlm.nih.gov/pubmed/18841992
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol802123e
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