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Theoretical Studies of [2,3]-Sigmatropic Rearrangements of Allylic Selenoxides and Selenimides

Density-functional theory is used to model the endo and exo transition states for [2,3]-sigmatropic rearrangement of allylic aryl-selenoxides and -selenimides. The endo transition state is generally preferred for selenoxides if there is no substitution at the 2 position of the allyl group. Based upo...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Bayse, Craig A., Antony, Sonia
Formato: Artigo
Idioma:Inglês
Publicado em: Molecular Diversity Preservation International 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6254911/
https://ncbi.nlm.nih.gov/pubmed/19783921
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules14093229
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