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Catalytic Enantioselective [2,3]-Rearrangements of Allylic Ammonium Ylides: A Mechanistic and Computational Study
[Image: see text] A mechanistic study of the isothiourea-catalyzed enantioselective [2,3]-rearrangement of allylic ammonium ylides is described. Reaction kinetic analyses using (19)F NMR and density functional theory computations have elucidated a reaction profile and allowed identification of the c...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , , , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
American Chemical
Society
2017
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| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5374492/ https://ncbi.nlm.nih.gov/pubmed/28230365 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b11851 |
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