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Copper-Catalyzed Enantioselective, Diastereoselective, and Regioselective [2,3]-Rearrangements of Iodonium Ylides

The first highly enantioselective, diastereoselective, and regioselective [2,3]-rearrangement of iodonium ylides has been developed as a general solution to catalytic onium ylide rearrangements. In the presence of a chiral copper catalyst, substituted allylic iodides couple with α-diazoesters to gen...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Xu, Bin, Tambar, Uttam K.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5674996/
https://ncbi.nlm.nih.gov/pubmed/28600841
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201705317
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