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Copper-catalyzed [1,2]-rearrangements of allylic iodides and aryl α-diazoacetates
The [1,2]- and [2,3]-rearrangements of iodonium ylides are synthetically useful reactions for the generation of functionalized α-iodoesters. Allylic iodides are coupled with α-diazoesters in the presence of a copper catalyst and a ligand to generate iodonium ylides, which undergo metal-mediated rear...
Tallennettuna:
| Julkaisussa: | Tetrahedron |
|---|---|
| Päätekijät: | , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2017
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5614460/ https://ncbi.nlm.nih.gov/pubmed/28966401 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2017.01.048 |
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