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Enantioselective Aryl-Iodide-Catalyzed Wagner–Meerwein Rearrangements
We report a strategy for effecting catalytic, enantioselective carbocationic rearrangements through the intermediacy of alkyl iodanes as stereodefined carbocation equivalents. Asymmetric Wagner–Meerwein rearrangements of β-substituted styrenes are catalyzed by the C(2)-symmetric aryl iodide 1 to pro...
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| Publicat a: | J Am Chem Soc |
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| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2020
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7523190/ https://ncbi.nlm.nih.gov/pubmed/32845619 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c08150 |
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