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Copper-Catalyzed Carboxylation of Aryl Iodides with Carbon Dioxide
A method for carboxylation of aryl iodides with carbon dioxide has been developed. The reaction employs low loadings of copper iodide/TMEDA or DMEDA catalyst, 1 atm of CO(2), DMSO or DMA solvent, and proceeds at 25–70 °C. Good functional group tolerance is observed, with ester, bromide, chloride, fl...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2013
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3839347/ https://ncbi.nlm.nih.gov/pubmed/24288654 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/cs400443p |
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