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Copper-Catalyzed Arylation of 1H-Perfluoroalkanes

A general method has been developed for arylation of readily available 1H-perfluoroalkanes. The method employs aryl iodide and 1H-perfluoroalkane reagents, DMPU solvent, TMP(2)Zn base, and a copper chloride/phenanthroline catalyst. Preliminary mechanistic studies are reported.

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Detalhes bibliográficos
Main Authors: Popov, Ilya, Lindeman, Sergey, Daugulis, Olafs
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3122272/
https://ncbi.nlm.nih.gov/pubmed/21627068
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2041942
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